Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract

<b>Background/Objectives</b>: Natural products are gaining increasing importance due to the large variety of biological activities exerted by their constituents. Among these, the products deriving from <i>Acmella oleracea</i> (L.) R.K. Jansen can be exploited for their local...

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Main Authors: Eleonora Spinozzi, Marco Cespi, Marta Ferrati, Riccardo Petrelli, Filippo Maggi, Junbiao Wang, Sunday Segun Alimi, Diego Romano Perinelli, Giulia Bonacucina
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Pharmaceutics
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Online Access:https://www.mdpi.com/1999-4923/17/5/625
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author Eleonora Spinozzi
Marco Cespi
Marta Ferrati
Riccardo Petrelli
Filippo Maggi
Junbiao Wang
Sunday Segun Alimi
Diego Romano Perinelli
Giulia Bonacucina
author_facet Eleonora Spinozzi
Marco Cespi
Marta Ferrati
Riccardo Petrelli
Filippo Maggi
Junbiao Wang
Sunday Segun Alimi
Diego Romano Perinelli
Giulia Bonacucina
author_sort Eleonora Spinozzi
collection DOAJ
description <b>Background/Objectives</b>: Natural products are gaining increasing importance due to the large variety of biological activities exerted by their constituents. Among these, the products deriving from <i>Acmella oleracea</i> (L.) R.K. Jansen can be exploited for their local anaesthetic, myorelaxant, anti-inflammatory/analgesic, and antifungal properties. In this regard, there is a need to develop novel formulations for the topical delivery of <i>A. oleracea</i>-derived extracts to widen their use in the pharmaceutical and cosmetic fields. <b>Methods</b>: Nanoformulations, i.e., nanoemulsions (NEs) and microemulsions (MEs), were investigated as a strategy to encapsulate an extract from <i>A. oleracea</i> at the nanoscale level in water and then incorporated into xanthan gum-based hydrogels. <b>Results</b>: Only NEs provided a physically stable formulation, while the precipitation of solid hydrophobic components from the extract was observed during ME preparation under all tested conditions despite the use of ethyl oleate as an oily co-solvent. The optimized NE-based hydrogel remained physically stable over six months, as confirmed by rheological measurements and polarized optical microscope observation, without a phase separation phenomenon. Therefore, NEs resulted more suitable nanodispersed systems than MEs for the encapsulation of <i>A. oleracea</i> extract, which contains a large amount of hydrophobic constituents that are solid at room temperature. Furthermore, the sustained spilanthol release across an artificial membrane (Franz cell apparatus) and the cytotoxic profile on HaCaT cell line support its potential topical application. <b>Conclusions</b>: The outcomes of this study provided valuable insights into the formulation of <i>A. oleracea</i> extract, broadening its fields of applicability, including topical administration.
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spelling doaj-art-03c6719fb81341ddb7005a8d35b5dba12025-08-20T03:14:32ZengMDPI AGPharmaceutics1999-49232025-05-0117562510.3390/pharmaceutics17050625Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> ExtractEleonora Spinozzi0Marco Cespi1Marta Ferrati2Riccardo Petrelli3Filippo Maggi4Junbiao Wang5Sunday Segun Alimi6Diego Romano Perinelli7Giulia Bonacucina8Chemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalySchool of Biosciences and Veterinary Medicine, University of Camerino, 62032 Camerino, ItalySchool of Biosciences and Veterinary Medicine, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, ItalyChemistry Interdisciplinary Project (ChIP), School of Pharmacy, University of Camerino, 62032 Camerino, Italy<b>Background/Objectives</b>: Natural products are gaining increasing importance due to the large variety of biological activities exerted by their constituents. Among these, the products deriving from <i>Acmella oleracea</i> (L.) R.K. Jansen can be exploited for their local anaesthetic, myorelaxant, anti-inflammatory/analgesic, and antifungal properties. In this regard, there is a need to develop novel formulations for the topical delivery of <i>A. oleracea</i>-derived extracts to widen their use in the pharmaceutical and cosmetic fields. <b>Methods</b>: Nanoformulations, i.e., nanoemulsions (NEs) and microemulsions (MEs), were investigated as a strategy to encapsulate an extract from <i>A. oleracea</i> at the nanoscale level in water and then incorporated into xanthan gum-based hydrogels. <b>Results</b>: Only NEs provided a physically stable formulation, while the precipitation of solid hydrophobic components from the extract was observed during ME preparation under all tested conditions despite the use of ethyl oleate as an oily co-solvent. The optimized NE-based hydrogel remained physically stable over six months, as confirmed by rheological measurements and polarized optical microscope observation, without a phase separation phenomenon. Therefore, NEs resulted more suitable nanodispersed systems than MEs for the encapsulation of <i>A. oleracea</i> extract, which contains a large amount of hydrophobic constituents that are solid at room temperature. Furthermore, the sustained spilanthol release across an artificial membrane (Franz cell apparatus) and the cytotoxic profile on HaCaT cell line support its potential topical application. <b>Conclusions</b>: The outcomes of this study provided valuable insights into the formulation of <i>A. oleracea</i> extract, broadening its fields of applicability, including topical administration.https://www.mdpi.com/1999-4923/17/5/625natural extractsalkylamidedynamic light scatteringnanoemulsion-based hydrogelmicroemulsionsrheology
spellingShingle Eleonora Spinozzi
Marco Cespi
Marta Ferrati
Riccardo Petrelli
Filippo Maggi
Junbiao Wang
Sunday Segun Alimi
Diego Romano Perinelli
Giulia Bonacucina
Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
Pharmaceutics
natural extracts
alkylamide
dynamic light scattering
nanoemulsion-based hydrogel
microemulsions
rheology
title Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
title_full Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
title_fullStr Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
title_full_unstemmed Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
title_short Hydrogels Powered by Nanoemulsion Technology for the Topical Delivery of <i>Acmella oleracea</i> Extract
title_sort hydrogels powered by nanoemulsion technology for the topical delivery of i acmella oleracea i extract
topic natural extracts
alkylamide
dynamic light scattering
nanoemulsion-based hydrogel
microemulsions
rheology
url https://www.mdpi.com/1999-4923/17/5/625
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