Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand
The synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/348475 |
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| author | Mohammad Tarique |
| author_facet | Mohammad Tarique |
| author_sort | Mohammad Tarique |
| collection | DOAJ |
| description | The synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the types ML2 {M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M'L3{M'=Cr(III) and Fe(III)} respectively. The conductometric measurements proved the non-electrolytic behaviour of all the compounds. The bidentate nature of dithiocarbamato moiety was confirmed on the basis of IR spectral data. |
| format | Article |
| id | doaj-art-0380ef3c60fb4bccba56a4c333796643 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-0380ef3c60fb4bccba56a4c3337966432025-02-03T01:24:13ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01842020202310.1155/2011/348475Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato LigandMohammad Tarique0Department of Engg Chemistry, Prem Prakash Gupta Institute of Engg., Bareilly(U.P.) – 243123, IndiaThe synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the types ML2 {M=Mn(II), Co(II), Ni(II), Cu(II) and Zn(II)} and M'L3{M'=Cr(III) and Fe(III)} respectively. The conductometric measurements proved the non-electrolytic behaviour of all the compounds. The bidentate nature of dithiocarbamato moiety was confirmed on the basis of IR spectral data.http://dx.doi.org/10.1155/2011/348475 |
| spellingShingle | Mohammad Tarique Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand E-Journal of Chemistry |
| title | Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand |
| title_full | Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand |
| title_fullStr | Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand |
| title_full_unstemmed | Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand |
| title_short | Cr(III),Mn(II),Fe(III),Co(II),Ni(II),Cu(II) and Zn(II) Complexes with Diisobutyldithiocarbamato Ligand |
| title_sort | cr iii mn ii fe iii co ii ni ii cu ii and zn ii complexes with diisobutyldithiocarbamato ligand |
| url | http://dx.doi.org/10.1155/2011/348475 |
| work_keys_str_mv | AT mohammadtarique criiimniifeiiicoiiniiicuiiandzniicomplexeswithdiisobutyldithiocarbamatoligand |