TiO2 phase-controlled synthesis of Li-La-TiO solid electrolytes for advanced all-solid-state batteries
This study focused on achieving high ionic conductivity in Li-La-TiO (LLTO) solid electrolyte. To enhance ionic conductivity, the synthesis reaction was optimized by controlling the composite crystal structure of TiO2 at the B-site of the perovskite (ABO3) structured LLTO, incorporating rutile, broo...
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| Main Authors: | , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Taylor & Francis Group
2024-10-01
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| Series: | Journal of Asian Ceramic Societies |
| Subjects: | |
| Online Access: | https://www.tandfonline.com/doi/10.1080/21870764.2024.2403258 |
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| Summary: | This study focused on achieving high ionic conductivity in Li-La-TiO (LLTO) solid electrolyte. To enhance ionic conductivity, the synthesis reaction was optimized by controlling the composite crystal structure of TiO2 at the B-site of the perovskite (ABO3) structured LLTO, incorporating rutile, brookite, and anatase phases. The solid-phase LLTO, synthesized utilizing the core – shell structured composite-phase TiO2 developed in this study for the first time, successfully transformed its crystal structure to β-LLTO (tetragonal to cubic). This resulted in a significant improvement in ionic conductivity (i.e. 1.11 × 10−4 Scm−1). The study findings confirmed that the composite crystal structure TiO2 used in the solid-phase synthesis of LLTO induced an increase in oxygen vacancies during the synthesis process, thereby reducing the step-free energy required for the final synthesis. |
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| ISSN: | 2187-0764 |