Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders

TLPS (Transient Liquid Phase Sintering) process is a candidate method of heat-resistant bonding, which makes use of the reaction between low-melting temperature powder of Sn-Bi base alloys and reactive powder of Ag. During heat treatment above the melting temperature of a Sn-Bi base alloy, the m...

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Main Authors: Ohnuma I., Kainuma R., Ishida K.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2012-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200052O.pdf
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author Ohnuma I.
Kainuma R.
Ishida K.
author_facet Ohnuma I.
Kainuma R.
Ishida K.
author_sort Ohnuma I.
collection DOAJ
description TLPS (Transient Liquid Phase Sintering) process is a candidate method of heat-resistant bonding, which makes use of the reaction between low-melting temperature powder of Sn-Bi base alloys and reactive powder of Ag. During heat treatment above the melting temperature of a Sn-Bi base alloy, the molten Sn-Bi reacts rapidly with solid Ag particles, which results in the formation of heat-resistant intermetallic compound (IMC). In this study, the TLPS properties between Sn-17Bi-1Ag (at.%) powder with its liquidus temperature of 200°C and pure Ag powder were investigated. During differential scanning calorimetry (DSC) measurement, an exothermic reaction and an endothermic reaction occurred, which correspond to the formation of the e-Ag3Sn IMC phase and the melting of the Sn-17Bi-1Ag alloy, respectively. After the overall measurement, the obtained reactant consists of the Ag3Sn-IMC and Bi-rich phases, both of which start melting above 250°C, with a small amount of the residual Sn-Bi eutectic phase. These results suggest that the TLPS process can be applied for Pb-free heatresistant bonding.
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publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-00ffa2d253794849a33d91159f8bda952025-02-02T07:03:45ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392012-01-0148341341810.2298/JMMB121123052ODevelopment of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powdersOhnuma I.Kainuma R.Ishida K.TLPS (Transient Liquid Phase Sintering) process is a candidate method of heat-resistant bonding, which makes use of the reaction between low-melting temperature powder of Sn-Bi base alloys and reactive powder of Ag. During heat treatment above the melting temperature of a Sn-Bi base alloy, the molten Sn-Bi reacts rapidly with solid Ag particles, which results in the formation of heat-resistant intermetallic compound (IMC). In this study, the TLPS properties between Sn-17Bi-1Ag (at.%) powder with its liquidus temperature of 200°C and pure Ag powder were investigated. During differential scanning calorimetry (DSC) measurement, an exothermic reaction and an endothermic reaction occurred, which correspond to the formation of the e-Ag3Sn IMC phase and the melting of the Sn-17Bi-1Ag alloy, respectively. After the overall measurement, the obtained reactant consists of the Ag3Sn-IMC and Bi-rich phases, both of which start melting above 250°C, with a small amount of the residual Sn-Bi eutectic phase. These results suggest that the TLPS process can be applied for Pb-free heatresistant bonding.http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200052O.pdfTransient Liquid Phase Sintering (TLPS)CALPHADhigh-tepmerature Pb-free solder
spellingShingle Ohnuma I.
Kainuma R.
Ishida K.
Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
Journal of Mining and Metallurgy. Section B: Metallurgy
Transient Liquid Phase Sintering (TLPS)
CALPHAD
high-tepmerature Pb-free solder
title Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
title_full Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
title_fullStr Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
title_full_unstemmed Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
title_short Development of heat resistant Pb-free joints by TLPS process of Ag and Sn-Bi-Ag alloy powders
title_sort development of heat resistant pb free joints by tlps process of ag and sn bi ag alloy powders
topic Transient Liquid Phase Sintering (TLPS)
CALPHAD
high-tepmerature Pb-free solder
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2012/1450-53391200052O.pdf
work_keys_str_mv AT ohnumai developmentofheatresistantpbfreejointsbytlpsprocessofagandsnbiagalloypowders
AT kainumar developmentofheatresistantpbfreejointsbytlpsprocessofagandsnbiagalloypowders
AT ishidak developmentofheatresistantpbfreejointsbytlpsprocessofagandsnbiagalloypowders