Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
PVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with in...
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Wiley
2013-01-01
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Series: | Advances in Condensed Matter Physics |
Online Access: | http://dx.doi.org/10.1155/2013/690629 |
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author | M. B. Nanda Prakash A. Manjunath R. Somashekar |
author_facet | M. B. Nanda Prakash A. Manjunath R. Somashekar |
author_sort | M. B. Nanda Prakash |
collection | DOAJ |
description | PVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with increase in CdCl2. AC conductivity in these polymer increases films first and then decreases. These observations are in agreement with XRD results. The highest ionic conductivity of 1.68E − 08 Scm−1 was observed in 4% of CdCl2 in PVA polymer blend. Crystallite ellipsoids for different concentrations of CdCl2 are computed here using whole pattern powder fitting (WPPF) indicating that crystallite area decreases with increase in the ionic conductivity. |
format | Article |
id | doaj-art-00283228cbd64147b254c6d5cc490034 |
institution | Kabale University |
issn | 1687-8108 1687-8124 |
language | English |
publishDate | 2013-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Condensed Matter Physics |
spelling | doaj-art-00283228cbd64147b254c6d5cc4900342025-02-03T05:50:11ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242013-01-01201310.1155/2013/690629690629Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer ElectrolyteM. B. Nanda Prakash0A. Manjunath1R. Somashekar2Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore, Karnataka 570006, IndiaDepartment of Studies in Physics, Government Science College, Chitradurga, Karnataka 577501, IndiaDepartment of Studies in Physics, University of Mysore, Manasagangotri, Mysore, Karnataka 570006, IndiaPVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with increase in CdCl2. AC conductivity in these polymer increases films first and then decreases. These observations are in agreement with XRD results. The highest ionic conductivity of 1.68E − 08 Scm−1 was observed in 4% of CdCl2 in PVA polymer blend. Crystallite ellipsoids for different concentrations of CdCl2 are computed here using whole pattern powder fitting (WPPF) indicating that crystallite area decreases with increase in the ionic conductivity.http://dx.doi.org/10.1155/2013/690629 |
spellingShingle | M. B. Nanda Prakash A. Manjunath R. Somashekar Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte Advances in Condensed Matter Physics |
title | Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte |
title_full | Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte |
title_fullStr | Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte |
title_full_unstemmed | Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte |
title_short | Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte |
title_sort | studies on ac electrical conductivity of cdcl2 doped pva polymer electrolyte |
url | http://dx.doi.org/10.1155/2013/690629 |
work_keys_str_mv | AT mbnandaprakash studiesonacelectricalconductivityofcdcl2dopedpvapolymerelectrolyte AT amanjunath studiesonacelectricalconductivityofcdcl2dopedpvapolymerelectrolyte AT rsomashekar studiesonacelectricalconductivityofcdcl2dopedpvapolymerelectrolyte |