Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte

PVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with in...

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Main Authors: M. B. Nanda Prakash, A. Manjunath, R. Somashekar
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2013/690629
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author M. B. Nanda Prakash
A. Manjunath
R. Somashekar
author_facet M. B. Nanda Prakash
A. Manjunath
R. Somashekar
author_sort M. B. Nanda Prakash
collection DOAJ
description PVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with increase in CdCl2. AC conductivity in these polymer increases films first and then decreases. These observations are in agreement with XRD results. The highest ionic conductivity of 1.68E − 08 Scm−1 was observed in 4% of CdCl2 in PVA polymer blend. Crystallite ellipsoids for different concentrations of CdCl2 are computed here using whole pattern powder fitting (WPPF) indicating that crystallite area decreases with increase in the ionic conductivity.
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institution Kabale University
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series Advances in Condensed Matter Physics
spelling doaj-art-00283228cbd64147b254c6d5cc4900342025-02-03T05:50:11ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242013-01-01201310.1155/2013/690629690629Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer ElectrolyteM. B. Nanda Prakash0A. Manjunath1R. Somashekar2Department of Studies in Physics, University of Mysore, Manasagangotri, Mysore, Karnataka 570006, IndiaDepartment of Studies in Physics, Government Science College, Chitradurga, Karnataka 577501, IndiaDepartment of Studies in Physics, University of Mysore, Manasagangotri, Mysore, Karnataka 570006, IndiaPVA-based polymer electrolytes were prepared with various concentrations of CdCl2 using solvent casting method. Prepared polymer films were investigated using line profile analysis employing X-ray diffraction (XRD) data. XRD results show that the crystallite size decreases and then increases with increase in CdCl2. AC conductivity in these polymer increases films first and then decreases. These observations are in agreement with XRD results. The highest ionic conductivity of 1.68E − 08 Scm−1 was observed in 4% of CdCl2 in PVA polymer blend. Crystallite ellipsoids for different concentrations of CdCl2 are computed here using whole pattern powder fitting (WPPF) indicating that crystallite area decreases with increase in the ionic conductivity.http://dx.doi.org/10.1155/2013/690629
spellingShingle M. B. Nanda Prakash
A. Manjunath
R. Somashekar
Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
Advances in Condensed Matter Physics
title Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
title_full Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
title_fullStr Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
title_full_unstemmed Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
title_short Studies on AC Electrical Conductivity of CdCl2 Doped PVA Polymer Electrolyte
title_sort studies on ac electrical conductivity of cdcl2 doped pva polymer electrolyte
url http://dx.doi.org/10.1155/2013/690629
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AT rsomashekar studiesonacelectricalconductivityofcdcl2dopedpvapolymerelectrolyte